Crystallography of the Polymethylene Chain: An Inquiry into the Structure of Waxes
Douglas L. Dorset
Published online:
01 September 2007
Published in print:
09 December 2004
Online ISBN:
9780191712838
Print ISBN:
9780198529088
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Crystallography of the Polymethylene Chain: An Inquiry into the Structure of Waxes
Douglas L. Dorset
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DOUGLAS L. DORSET
Pages
33–56
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Published:
December 2004
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DORSET, DOUGLAS L., 'Crystal structures and phase transitions of the paraffins', Crystallography of the Polymethylene Chain: An Inquiry into the Structure of Waxes, International Union of Crystallography Monographs on Crystallography (
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Abstract
This chapter discusses the known crystal structures of n-paraffins. Important variables include chain length, chain parity (odd-even), and chain folding. The existence of various polymorphic forms is demonstrated for many materials. The influences of small chain substitutions, such as methyl branching or addition of an aromatic group, on layer packing are introduced.
Keywords: n-paraffins, cycloalkanes, methyl-branched paraffins, polyethylene
Subject
Condensed Matter Physics Crystallography
Collection: Oxford Scholarship Online
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