Dehydrogenation of long chain n-paraffins to olefins – a perspective (2024)

He, S., Krishnamurthy, K. R., & Seshan, K. (2017). Dehydrogenation of long chain n-paraffins to olefins – a perspective. In J. Spivey, & Y. Han (editors), Catalysis (Vol. 29, blz. 282-316). Royal Society of Chemistry. https://doi.org/10.1039/9781788010634-00282

He, Songbo ; Krishnamurthy, K. R. ; Seshan, K. / Dehydrogenation of long chain n-paraffins to olefins – a perspective. Catalysis. redacteur / James Spivey ; Yifan Han. Vol. 29 Royal Society of Chemistry, 2017. blz. 282-316

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title = "Dehydrogenation of long chain n-paraffins to olefins – a perspective",

abstract = "Dehydrogenation of long chain n-paraffins, in the carbon number range C10–C14, is a key step in the process for manufacture of bio-degradable synthetic detergent raw material, Linear Alkyl Benzene (LAB). Since its discovery in 1968, the process has undergone several improvements in the architecture of dehydrogenation catalysts towards achieving higher selectivity for mono-olefins formation, increase in LAB yield and quality, raw materials consumption and minimization of by-products, accompanied by several modifications in the process steps. This chapter brings out the salient features of the basic chemistry behind the dehydrogenation process, the catalyst characteristics, process chemistry, thermodynamics, kinetic and mechanistic aspects, traces the developments in the catalysts and process for dehydrogenation and finally, a brief on the emerging process technologies.",

author = "Songbo He and Krishnamurthy, {K. R.} and K. Seshan",

year = "2017",

doi = "10.1039/9781788010634-00282",

language = "English",

isbn = "978-1-78262-956-6",

volume = "29",

pages = "282--316",

editor = "James Spivey and Yifan Han",

booktitle = "Catalysis",

publisher = "Royal Society of Chemistry",

}

He, S, Krishnamurthy, KR & Seshan, K 2017, Dehydrogenation of long chain n-paraffins to olefins – a perspective. in J Spivey & Y Han (uitgave), Catalysis. vol. 29, Royal Society of Chemistry, blz. 282-316. https://doi.org/10.1039/9781788010634-00282

Dehydrogenation of long chain n-paraffins to olefins – a perspective. / He, Songbo; Krishnamurthy, K. R.; Seshan, K.
Catalysis. uitgave / James Spivey; Yifan Han. Vol. 29 Royal Society of Chemistry, 2017. blz. 282-316.

Onderzoeksoutput › Academic › peer review

TY - CHAP

T1 - Dehydrogenation of long chain n-paraffins to olefins – a perspective

AU - He, Songbo

AU - Krishnamurthy, K. R.

AU - Seshan, K.

PY - 2017

Y1 - 2017

N2 - Dehydrogenation of long chain n-paraffins, in the carbon number range C10–C14, is a key step in the process for manufacture of bio-degradable synthetic detergent raw material, Linear Alkyl Benzene (LAB). Since its discovery in 1968, the process has undergone several improvements in the architecture of dehydrogenation catalysts towards achieving higher selectivity for mono-olefins formation, increase in LAB yield and quality, raw materials consumption and minimization of by-products, accompanied by several modifications in the process steps. This chapter brings out the salient features of the basic chemistry behind the dehydrogenation process, the catalyst characteristics, process chemistry, thermodynamics, kinetic and mechanistic aspects, traces the developments in the catalysts and process for dehydrogenation and finally, a brief on the emerging process technologies.

AB - Dehydrogenation of long chain n-paraffins, in the carbon number range C10–C14, is a key step in the process for manufacture of bio-degradable synthetic detergent raw material, Linear Alkyl Benzene (LAB). Since its discovery in 1968, the process has undergone several improvements in the architecture of dehydrogenation catalysts towards achieving higher selectivity for mono-olefins formation, increase in LAB yield and quality, raw materials consumption and minimization of by-products, accompanied by several modifications in the process steps. This chapter brings out the salient features of the basic chemistry behind the dehydrogenation process, the catalyst characteristics, process chemistry, thermodynamics, kinetic and mechanistic aspects, traces the developments in the catalysts and process for dehydrogenation and finally, a brief on the emerging process technologies.

U2 - 10.1039/9781788010634-00282

DO - 10.1039/9781788010634-00282

M3 - Chapter

SN - 978-1-78262-956-6

VL - 29

SP - 282

EP - 316

BT - Catalysis

A2 - Spivey, James

A2 - Han, Yifan

PB - Royal Society of Chemistry

ER -

He S, Krishnamurthy KR, Seshan K. Dehydrogenation of long chain n-paraffins to olefins – a perspective. In Spivey J, Han Y, redacteurs, Catalysis. Vol. 29. Royal Society of Chemistry. 2017. blz. 282-316 doi: 10.1039/9781788010634-00282